Premium
[12.12]Paracyclophanedodecaynes C 36 H 8 and C 36 Cl 8 : The Smallest Paracyclophynes and Their Transformation into the Carbon Cluster Ion C 36 −
Author(s) -
Tobe Yoshito,
Furukawa Ryutaro,
Sonoda Motohiro,
Wakabayashi Tomonari
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20011105)40:21<4072::aid-anie4072>3.0.co;2-v
Subject(s) - cluster (spacecraft) , work (physics) , derivative (finance) , carbon fibers , ion , chlorine , transformation (genetics) , computer science , chemistry , library science , physics , organic chemistry , business , algorithm , operating system , thermodynamics , finance , composite number , biochemistry , gene
The smallest [ n.n ]cyclophyne known, [12.12]paracyclophanedodecaynes C 36 H 8 and C 36 Cl 8 (see picture), were generated by [2+2] cycloreversion of its precursor under photolytic and mass spectrometric conditions. The stepwise loss of chlorine atoms from the anion of the octachloro derivative C 36 Cl 8 − produced a carbon cluster anion C 36 − in the gas phase.