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Monolithic Materials: New High‐Performance Supports for Permanently Immobilized Metathesis Catalysts
Author(s) -
Mayr Monika,
Mayr Betina,
Buchmeiser Michael R.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20011015)40:20<3839::aid-anie3839>3.0.co;2-o
Subject(s) - metathesis , ring opening metathesis polymerisation , polymerization , derivatization , materials science , catalysis , microstructure , scanning electron microscope , salt metathesis reaction , chemical engineering , polymer chemistry , chemistry , organic chemistry , polymer , composite material , high performance liquid chromatography , engineering
Back to the roots : Ring‐opening metathesis polymerization allows the synthesis of monolithic materials, which may be subject to an in situ derivatization with dihydroimidazolium salts through metathesis graft polymerization. This method offers an attractive route to highly reactive, permanently immobilized metathesis initiators. The picture shows an electron microscope image of the microstructure of the monolithic support.