Premium
The Self‐Assembly of an Unexpected, Unique Supramolecular Triangle Composed of Rigid Subunits
Author(s) -
Schweiger Manuela,
Seidel S. Russell,
Arif Atta M.,
Stang Peter J.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010917)40:18<3467::aid-anie3467>3.0.co;2-4
Subject(s) - supramolecular chemistry , linker , pyrazine , platinum , solid state , square (algebra) , crystallography , chemistry , center (category theory) , stereochemistry , materials science , mathematics , computer science , catalysis , crystal structure , organic chemistry , geometry , operating system
A supramolecular triangle results , instead of the expected square, from the reaction of a compact, ditopic 90° platinum( II ) center and the most rigid, aromatic linear linker, pyrazine (see picture). This unexpected species is characterized both in solution and the solid state.