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Synthesis and Structural Characterization of the First Uranium Cluster Containing an Isopolyoxometalate Core
Author(s) -
Duval Paul B.,
Burns Carol J.,
Clark David L.,
Morris David E.,
Scott Brian L.,
Thompson Joe D.,
Werkema Evan L.,
Jia Li,
Andersen Richard A.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010917)40:18<3357::aid-anie3357>3.0.co;2-c
Subject(s) - actinide , uranium , core (optical fiber) , characterization (materials science) , cluster (spacecraft) , derivative (finance) , content (measure theory) , chemistry , library science , computer science , nanotechnology , physics , materials science , nuclear physics , nuclear chemistry , mathematics , business , programming language , telecommunications , mathematical analysis , finance
Known for the Group 6 metals for over 100 years , the family of isopolyoxometalates has now been extended to include the first uranium derivative 1 , which contains a [U 6 O 13 ] core. In comparison to the well‐studied transition metal analogues, the structural and electronic properties of 1 reflect the chemical attributes of the actinides. Cp ≠ =1,2,4‐ t Bu 3 C 5 H 2 .