Catalytic C−H Activation of sp 3  C−H Bonds in  α ‐Position to a Nitrogen Atom—Two New Approaches | Zendy

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Catalytic C−H Activation of sp 3 C−H Bonds in α ‐Position to a Nitrogen Atom—Two New Approaches

Author(s) -

Doye Sven

Publication year - 2001

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/1521-3773(20010917)40:18<3351::aid-anie3351>3.0.co;2-b

Subject(s) - iridium , rhodium , catalysis , nitrogen atom , atom (system on chip) , nitrogen , chemistry , transition metal , cyclooctadiene , position (finance) , stereochemistry , organic chemistry , group (periodic table) , computer science , embedded system , finance , economics

A very promising approach for the efficient synthesis of complex amines is provided by the transition metal catalyzed activation of sp 3 C−H bonds in the position α to a nitrogen atom. Two recent publications show that this approach can be realized impressively by the use of rhodium and iridium catalysts (see scheme; cod=1,5‐cyclooctadiene).

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