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Flexible meso ‐Bis(sulfinyl) Ligands as Building Blocks for Copper( II ) Coordination Polymers: Cavity Control by Varying the Chain Length of Ligands
Author(s) -
Bu XianHe,
Chen Wei,
Lu ShouLiang,
Zhang RuoHua,
Liao DaiZheng,
Bu WeiMing,
Shionoya Mitsuhiko,
Brisse Francois,
Ribas Joan
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010903)40:17<3201::aid-anie3201>3.0.co;2-z
Subject(s) - copper , chain (unit) , octahedron , antiferromagnetism , crystallography , chemistry , metal , polymer , coordination polymer , stereochemistry , materials science , crystal structure , organic chemistry , physics , condensed matter physics , astronomy
Fillings and cavities : Three novel pseudo‐octahedral metal–organic frameworks, 1 – 3 , consisting of macrometallacyclic noninterpenetrating meso networks and exhibiting weak antiferromagnetic interactions, have been constructed from Cu II centers and structurally flexible R , S ‐bis(sulfinyl) ligands. Varying the chain length of ligands is found to control the cavity sizes of the networks.