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Transition Metal Complexes with the Proton Sponge 4,9‐Dichloroquino[7,8‐ h ]quinoline: Highly Twisted Aromatic Systems and an Extreme “Out‐of‐Plane” Position of the Coordinated Transition Metal Atom
Author(s) -
Wüstefeld HansUlrich,
Kaska William C.,
Schüth Ferdi,
Stucky Galen D.,
Bu Xianhui,
Krebs Bernt
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010903)40:17<3182::aid-anie3182>3.0.co;2-j
Subject(s) - transition metal , quinoline , atom (system on chip) , ligand (biochemistry) , proton , catalysis , metal , thermal stability , crystallography , chemistry , materials science , photochemistry , organic chemistry , physics , nuclear physics , biochemistry , receptor , computer science , embedded system
An extremely high thermal and chemical stability as well as a unique “out‐of‐plane” position of the metal atom is shown by the first stable transition metal complexes formed with the proton sponge 1 as the ligand. The properties of these complexes await wide application in catalysis and medicine.