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Homoleptic Azidometalates
Author(s) -
Kornath Andreas
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010903)40:17<3135::aid-anie3135>3.0.co;2-b
Subject(s) - homoleptic , philosophy , chemistry , organic chemistry , metal
Azidometalates are not explosive if the solid salts contain sufficiently large cations. Structure determinations on single crystals of such compounds elucidate how the azide ions (see picture) act as covalently bound ligands and have several different bridging modes.