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A More Efficient Catalyst for the Carbonylation of Chloroarenes
Author(s) -
Mägerlein Wolfgang,
Indolese Adriano F.,
Beller Matthias
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010803)40:15<2856::aid-anie2856>3.0.co;2-1
Subject(s) - carbonylation , catalysis , chemistry , organic chemistry , carbon monoxide
The right ligand enables the efficient carbonylation of unactivated chloroarenes. A general synthesis of benzoic acid derivatives is possible with the palladium–ferrocenylphosphane catalysts (see scheme).