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A Novel Hemiporphyrazine Comprising Three Isoindolediimine and Three Thiadiazole Units
Author(s) -
Kobayashi Nagao,
Inagaki Sayaka,
Nemykin Victor N.,
omura Taro
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010716)40:14<2710::aid-anie2710>3.0.co;2-a
Subject(s) - condensation , ring (chemistry) , computer science , chemistry , contrast (vision) , information retrieval , combinatorial chemistry , combinatorics , stereochemistry , mathematics , organic chemistry , physics , artificial intelligence , meteorology
Incorporation of three metal ions (Ni or Cu) in the macrocyclic ring and the formation of hexamers following a 3+3 approach are novel features of the hemiporphyrazines (one example shown) formed by the condensation of 2,5‐diamino‐1,3,4‐triazole with isoindolediimines. This is in contrast to the corresponding reactions with diaminotriazoles, which afford 2+2 products.