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Barium Triphenylmethanide: An Examination of Anion Basicity
Author(s) -
Alexander Jacob S.,
RuhlandtSenge Karin
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010716)40:14<2658::aid-anie2658>3.0.co;2-y
Subject(s) - barium , ion , chemistry , crown ether , cleavage (geology) , ether , inorganic chemistry , materials science , organic chemistry , fracture (geology) , composite material
Differences in anion basicity seem to be key for the formation of the first charge‐separated barium triphenylmethanide (see structure) versus a novel heteroleptic vinyl ether which results from cleavage of the attendant [18]crown‐6. Ba: green; O: red; P: yellow; N: blue.