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Oxide Addition to a Reactive Polysulfide Flux: Synthesis of K 4 Ba[Ti 6 OS 20 ] Containing Isolated [Ti 6 OS 8 (S 2 ) 6 ] 6− Clusters
Author(s) -
Huang Fu Qiang,
Ibers James A.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010702)40:13<2515::aid-anie2515>3.0.co;2-0
Subject(s) - polysulfide , cluster (spacecraft) , flux (metallurgy) , oxide , chemistry , ion , materials science , inorganic chemistry , crystallography , organic chemistry , computer science , electrode , electrolyte , programming language
The zero‐dimensional cluster compound K 4 Ba[Ti 6 OS 8 (S 2 ) 6 ] has been synthesized from a reactive flux similar to that of K 2 S n and Ti used in the synthesis of the one‐dimensional compound K 4 Ti 3 S 14 , but augmented by the deliberate introduction of TiO 2 . The picture shows the structure of the [Ti 6 OS 8 (S 2 ) 6 ] 6− ion.