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Synthesis of a Remarkably Stable Dehydro[14]annulene
Author(s) -
Palmer Grant J.,
Parkin Sean R.,
Anthony John E.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010702)40:13<2509::aid-anie2509>3.0.co;2-f
Subject(s) - annulene , chemistry , stability (learning theory) , stereochemistry , mathematics , computational chemistry , computer science , machine learning
The substituents at the peri positions of dehydro[14]annulenes 1 have a dramatic effect on the stability of these macrocycles, and lead to derivatives that are stable even at elevated temperatures (up to 190°C).