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Tetrathiafulvaleno‐Annelated Porphyrins
Author(s) -
Becher Jan,
Brimert Thomas,
Jeppesen Jan O.,
Pedersen Jens Z.,
Zubarev Roman,
Bjørnholm Thomas,
Reitzel Niels,
Jensen Torben R.,
Kjaer Kristian,
Levillain Eric
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010702)40:13<2497::aid-anie2497>3.0.co;2-f
Subject(s) - porphyrin , variety (cybernetics) , electron paramagnetic resonance , cyclic voltammetry , mass spectrometry , spectroscopy , diffraction , chemistry , analytical chemistry (journal) , computer science , organic chemistry , physics , optics , electrochemistry , nuclear magnetic resonance , artificial intelligence , chromatography , electrode , quantum mechanics
Two efficient synthetic routes to the first tetrathiafulvaleno‐annelated porphyrins are reported. These novel porphyrin systems (see picture; Pe=pentyl) have been characterized by using a variety of techniques including EPR spectroscopy, cyclic voltammetry, and mass spectrometry. Langmuir–Blodgett films obtained from the porphyrins were used to carry out structural studies by using X‐ray diffraction and atomic force microscopy.