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Base‐Assisted Formation of Organozirconium Oxides with the [Zr 6 ( μ 6 ‐O)( μ 3 ‐O) 8 ] Core Structure
Author(s) -
Bai Guangcai,
Roesky Herbert W.,
Lobinger Peter,
Noltemeyer Mathias,
Schmidt HansGeorg
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010601)40:11<2156::aid-anie2156>3.0.co;2-e
Subject(s) - mesitylene , toluene , solvent , oxide , chemistry , cluster (spacecraft) , core (optical fiber) , phase (matter) , base (topology) , inorganic chemistry , materials science , organic chemistry , computer science , mathematical analysis , mathematics , programming language , composite material
KH and the two‐phase system liquid ammonia/toluene provide the basis for a new method for the synthesis of organozirconium oxides such as [{(EtMe 4 C 5 )Zr} 6 ( μ 6 ‐O)( μ 3 ‐ O) 8 ]⋅C 7 H 8 (the central inorganic core of the cluster is shown). Altering the solvent to mesitylene has no influence on the core structure of the resulting organozirconium oxide.