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Rapid Access to Complex Molecular Architectures via o ‐Azaquinones
Author(s) -
Nicolaou K. C.,
Zhong YongLi,
Baran Phil S.,
Sugita Kazyuki
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010601)40:11<2145::aid-anie2145>3.0.co;2-m
Subject(s) - multitude , natural product , product (mathematics) , chemistry , combinatorial chemistry , molecule , nanotechnology , computer science , stereochemistry , materials science , organic chemistry , mathematics , political science , geometry , law
A multitude of natural product like molecules such as 2 and 3 can be readily obtained from hydroxyketoamide 1 . The versatile 1 is derived, via the intermediate o ‐azaquinone 4 , from the Dess–Martin periodinane oxidation of the corresponding anilide.