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High‐Valent Manganese Corroles and the First Perhalogenated Metallocorrole Catalyst
Author(s) -
Golubkov Galina,
Bendix Jesper,
Gray Harry B.,
Mahammed Atif,
Goldberg Israel,
DiBilio Angel J.,
Gross Zeev
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010601)40:11<2132::aid-anie2132>3.0.co;2-5
Subject(s) - corrole , manganese , pyrrole , catalysis , porphyrin , chemistry , ligand (biochemistry) , styrene , redox , combinatorial chemistry , photochemistry , polymer chemistry , organic chemistry , copolymer , biochemistry , receptor , polymer
On pyrrole! The pyrrole‐based corrole ligands can offer an alternative to porphyrin systems. The manganese corroles 1 – 4 are readily synthesized, undergo metal‐ not ligand‐based redox chemistry, and 4 in particular shows impressive catalytic activity in the oxygenation of styrene with iodosylbenzene.