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Self‐Assembly of Nanometer‐Scale Secondary Building Units into an Undulating Two‐Dimensional Network with Two Types of Hydrophobic Cavity
Author(s) -
Bourne Susan A.,
Lu Jianjiang,
Mondal Arunendu,
Moulton Brian,
Zaworotko Michael J.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010601)40:11<2111::aid-anie2111>3.0.co;2-f
Subject(s) - sbus , nanometre , nanoscopic scale , scale (ratio) , polymer , materials science , series (stratigraphy) , nanotechnology , unit (ring theory) , crystallography , chemical physics , chemistry , physics , composite material , geology , mathematics , metal organic framework , adsorption , quantum mechanics , paleontology , mathematics education
A series of bowls separated by hour‐glass‐shaped channels characterizes the structure of the undulating two‐dimensional coordination polymer (see picture) that is prepared from a nanoscale secondary building unit (nSBU), which is formed by four square metal( II )carboxylate SBUs that have 1,3‐benzenedicarboxylate units as 120° spacers.