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A Striking, Multifaceted, Decalithium Aggregate with Carbanion, Organoamide, and Alkoxide Functionalities
Author(s) -
Andrews Philip C.,
Deacon Glen B.,
Forsyth Craig M.,
Scott Natalie M.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010601)40:11<2108::aid-anie2108>3.0.co;2-c
Subject(s) - alkoxide , carbanion , superbase , aggregate (composite) , lithium (medication) , chemistry , psychology , materials science , stereochemistry , organic chemistry , nanotechnology , psychiatry , catalysis
The three most important “superbase” anionic building blocks are contained in the striking decalithium aggregate in the structure of which a single lithium atom is surrounded solely by an amide, an alkoxide, and a carbanion (see picture).