Premium
A Novel Route to Fulvene Complexes of Titanium—Diastereoselective Complexation of Pentafulvenes to Cyclopentadienyltitanium Fragments
Author(s) -
Beckhaus Rüdiger,
Lützen Arne,
Haase Detlev,
Saak Wolfgang,
Stroot Jörg,
Becke Sigurd,
Heinrichs Jürgen
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010601)40:11<2056::aid-anie2056>3.0.co;2-k
Subject(s) - fulvene , chemistry , substitution (logic) , transition metal , titanium , coordination complex , computational chemistry , organic chemistry , combinatorial chemistry , photochemistry , metal , catalysis , computer science , programming language
An alternative to the known thermally induced syntheses of fulvene complexes of early transition metals is now provided by the direct reductive complexation of pentafulvenes to [CpTiCl] fragments. These generally highly diastereoselective reactions (see scheme) enable a broad variation of substitution patterns and establish an extensive subsequent chemistry.