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Mechanistic Rationale of a Palladium‐Catalyzed Allylic Substitution Polymerization—Carbon−Carbon Bond‐Forming Polycondensation out of Stoichiometric Control by Cascade Bidirectional Allylation
Author(s) -
Nomura Nobuyoshi,
Tsurugi Ko,
Okada Masahiko
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010518)40:10<1932::aid-anie1932>3.0.co;2-p
Subject(s) - allylic rearrangement , condensation polymer , substitution (logic) , polymerization , catalysis , stoichiometry , palladium , substitution reaction , chemistry , olefin fiber , cascade , polymer chemistry , carbon fibers , organic chemistry , materials science , polymer , computer science , chromatography , composite number , composite material , programming language
The reactions of transient olefin–L n Pd 0 complexes must be controlled for successful allylic‐substitution polymerization. These reactions reveal a novel aspect of C−C bond‐forming polycondensation (see scheme).