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A Homoleptic Carbene–Lithium Complex
Author(s) -
Fränkel Robert,
Birg Christine,
Kernbach Ulrich,
Habereder Tassilo,
Nöth Heinrich,
Fehlhammer Wolf P.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010518)40:10<1907::aid-anie1907>3.0.co;2-1
Subject(s) - homoleptic , carbene , lithium (medication) , chemistry , chelation , carbon fibers , boron , medicinal chemistry , inorganic chemistry , organic chemistry , materials science , catalysis , metal , medicine , composite number , composite material , endocrinology
Rarity value is something that main group complexes of N‐heterocyclic carbenes still have. With a triscarbene chelating carbon analogue of Trofimenko's tris(pyrazolyl)borate the solvent free, dinuclear lithium complex 1 was successfully synthesized, in which the lithium atoms are only bound to carbene carbon atoms.