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The First Barium–Carborate Complex: Synthesis and Structural Investigation
Author(s) -
Westerhausen Matthias,
Gückel Christian,
Schneiderbauer Stefan,
Nöth Heinrich,
Hosmane Narayan S.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010518)40:10<1902::aid-anie1902>3.0.co;2-v
Subject(s) - metalation , carborane , chemistry , barium , trimethylsilyl , stereochemistry , medicinal chemistry , organic chemistry
Short Ba−C bonds and a BaHB 2 four‐center bond characterize the baracarborane 1 , which was obtained by metalation of 2,3‐bis(trimethylsilyl)‐2,3‐dicarba‐ nido ‐hexaborane with [(thf) 4 Ba{Zn(CH 2 SiMe 3 ) 3 } 2 ]. A dialkylzinc side product reacts neither with the carborane nor with 1 .