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New Phosphorus Ligands for the Rhodium‐Catalyzed Isomerization/Hydroformylation of Internal Octenes
Author(s) -
Selent Detlef,
Hess Dieter,
Wiese KlausDiether,
Röttger Dirk,
Kunze Christine,
Börner Armin
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010504)40:9<1696::aid-anie16960>3.0.co;2-2
Subject(s) - hydroformylation , isomerization , rhodium , catalysis , selectivity , chemistry , organic chemistry
Going up! n ‐Selectivity and activity can be increased simultaneously in hydroformylation by the use of novel hybrid ligands such as 1 containing O ‐acylphosphite groups. For the first time these ligands deliver impressively n ‐selective rhodium‐catalyzed hydroformylation of internal octenes, and this with an industrial relevant catalytic activity.