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Dodeca(benzyloxy)dodecaborane, B 12 (OCH 2 Ph) 12 : A Stable Derivative of hypercloso ‐B 12 H 12
Author(s) -
Peymann Toralf,
Knobler Carolyn B.,
Khan Saeed I.,
Hawthorne M. Frederick
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010504)40:9<1664::aid-anie16640>3.0.co;2-o
Subject(s) - derivative (finance) , economics , financial economics
Per‐O‐benzylation of [ closo ‐B 12 (OH) 12 ] 2− ( 1 2− ) using benzyl chloride followed by oxidation with two equivalents of Fe III gave compound 2 , the per(benzyloxy) derivative of hypercloso ‐B 12 H 12 (see scheme). Species 2 is characterized by 11 B NMR and electronic spectroscopy, mass spectrometry, cyclic voltammetry, and X‐ray crystallography.