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First Example of the μ 3 ‐ η 1 , η 2 , η 1 ‐C 60 Bonding Mode: Ligand‐Induced Conversion of π to σ C 60 –Metal Complexes
Author(s) -
Song Hyunjoon,
Lee Kwangyeol,
Lee Chang H.,
Park Joon T.,
Chang Hong Y.,
Choi MoonGun
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010417)40:8<1500::aid-anie1500>3.0.co;2-w
Subject(s) - ligand (biochemistry) , mode (computer interface) , ring (chemistry) , molecule , metal , chemistry , type (biology) , crystallography , computer science , stereochemistry , organic chemistry , biology , operating system , ecology , biochemistry , receptor
A boat‐shaped 1,4‐cyclohexadiene‐like ring is present in the C 60 molecule with a novel σ‐type μ 3 ‐ η 1 , η 2 , η 1 bonding mode in the clusters 2 a and 2 b . The change in coordination mode was induced by insertion of an RNC ligand into an Os−Os bond of the π‐type C 60 complex 1 . R=CH 2 C 6 H 5 .