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Ligand‐Controlled Chemoselectivity in the Classical Oxidative Addition Reactions of MeI and Aldehydes to Rhodium( I ) Complexes
Author(s) -
Goikhman Roman,
Milstein David
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010316)40:6<1119::aid-anie11190>3.0.co;2-n
Subject(s) - chemoselectivity , rhodium , ligand (biochemistry) , reactivity (psychology) , chemistry , oxidative addition , oxidative phosphorylation , combinatorial chemistry , medicinal chemistry , stereochemistry , organic chemistry , catalysis , biochemistry , receptor , medicine , alternative medicine , pathology
The strikingly different reactivity of similar complexes of the type [P n RhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].