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[30]Metallacrown‐10 Compounds: [Mn(C 14 H 9 N 2 O 3 )(CH 3 OH)] 10 ⋅5 CH 2 Cl 2 ⋅16 CH 3 OH⋅H 2 O and [Fe(C 14 H 9 N 2 O 3 )(CH 3 OH)] 10 ⋅3 CH 2 Cl 2 ⋅12.5 CH 3 OH⋅5 H 2 O
Author(s) -
Liu ShiXiong,
Lin Shen,
Lin BiZhou,
Lin ChiChang,
Huang JianQuan
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010316)40:6<1084::aid-anie10840>3.0.co;2-u
Subject(s) - ring (chemistry) , manganese , ligand (biochemistry) , crystallography , chemistry , metal , planar , core (optical fiber) , propeller , stereochemistry , materials science , organic chemistry , geology , receptor , computer science , biochemistry , computer graphics (images) , oceanography , composite material
A planar decanuclear 30‐membered core ring is present in the new manganese (see picture) and iron [30]azametallacrown‐10 compounds. These compounds were prepared by using the pentadentate ligand N ‐phenylsalicylhydrazidate, and the metal atoms in each ring adopt a propeller configuration and have alternating Λ / Δ stereochemistries.