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From Oligomers to Conducting Polymers of the Metal–Dinitrogen Functionality
Author(s) -
Solari Euro,
Hesschenbrouck Joëlle,
Scopelliti Rosario,
Floriani Carlo,
Re Nazzareno
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010302)40:5<932::aid-anie932>3.0.co;2-#
Subject(s) - polymer , metal , chemistry , polymer science , polymer chemistry , conductive polymer , nanotechnology , combinatorial chemistry , materials science , organic chemistry
A new avenue is opened up in the potential use of dinitrogen. Oligomerization of the metalla–dinitrogen functionality leads to the formation of polymers based on a [−(Mes) 3 W−N 2 −] n qmoiety (see picture).