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“Supramolecular” Solid‐State Chemistry: Interpenetrating Diamond‐Type Frameworks of U 4+ Ions Linked by S , S ′‐Bidentate P 2 S 6 2− Molecular Rods in UP 4 S 12
Author(s) -
Gieck Christine,
Rocker Frank,
Ksenofontov Vadim,
Gütlich Philipp,
Tremel Wolfgang
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010302)40:5<908::aid-anie908>3.0.co;2-o
Subject(s) - supramolecular chemistry , diamond , denticity , solid state , polymer , ion , crystallography , rod , materials science , chemistry , polymer chemistry , nanotechnology , crystal structure , organic chemistry , medicine , alternative medicine , pathology
Inseparably interwoven are three independent polymeric diamond‐type U(P 2 S 6 ) 2 frameworks in the structure of the title compound (see picture). The linear P 2 S 6 units act as molecular rods linking the pseudotetrahedral U 4+ centers. U(P 2 S 6 ) 2 may be viewed as a coordination polymer which is formed from U/P/S melts by the solid‐state equivalent of the self‐assembly reactions in solution.