Premium
Design and Synthesis of Foldamers Based on an Anthracene Diels–Alder Adduct
Author(s) -
Winkler Jeffrey D.,
Piatnitski Evgueni L.,
Mehlmann John,
Kasparec Jiri,
Axelsen Paul H.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010216)40:4<743::aid-anie7430>3.0.co;2-0
Subject(s) - anthracene , adduct , ring (chemistry) , tetrapeptide , chemistry , dipeptide , stereochemistry , diels–alder reaction , amino acid , organic chemistry , peptide , biochemistry , catalysis
A twelve‐membered hydrogen‐bonded ring and the resulting helical structure (see picture) in the tetrapeptide and an eight‐membered hydrogen‐bonded ring in the dipeptide illustrate the structural consequences of the incorporation of the novel β ‐amino acid derived from the Diels–Alder adduct of anthracene and dimenthyl fumarate.