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Thioformaldehyde S ‐sulfide (Thiosulfine)
Author(s) -
Mlostoń Grzegorz,
Romański Jaroslaw,
Reisenauer Hans Peter,
Maier Günther
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010119)40:2<393::aid-anie393>3.0.co;2-j
Subject(s) - ylide , matrix isolation , sulfide , pyrolysis , ring (chemistry) , spectroscopy , closure (psychology) , chemistry , materials science , infrared spectroscopy , organic chemistry , physics , quantum mechanics , economics , market economy
Matrix isolation spectroscopy allows the direct identification of ylide 1 and its cyclic isomer 2 . They were obtained by pyrolysis of 1,2,4‐trithiolane under high vacuum; the cyclic compound forms from 1 by thermal ring closure in a kinetically controlled reaction.