Premium
Singly and Doubly Oxidized Phthalocyanine (pc) Rings: [Cu(pc)(ReO 4 )] and [Cu(pc)(ReO 4 ) 2 ]
Author(s) -
Gardberg Anna S.,
Doan Peter E.,
Hoffman Brian M.,
Ibers James A.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20010105)40:1<244::aid-anie244>3.0.co;2-g
Subject(s) - perrhenate , phthalocyanine , ring (chemistry) , chemistry , copper , electron paramagnetic resonance , metal , crystallography , inorganic chemistry , rhenium , nuclear magnetic resonance , organic chemistry , physics
One ring, two oxidations : The first doubly ring‐oxidized metal phthalocyanine complex has been synthesized by galvanostatic electrocrystallization. Copper phthalocyanine was oxidized in the presence of perrhenate anions to form the new molecular compounds [Cu(pc)(ReO 4 )] and [Cu(pc)(ReO 4 ) 2 ] (structure shown). Single‐crystal EPR results show that the oxidation of [Cu(pc)(ReO 4 ) 2 ] is entirely ring‐based.