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New Family of Cyclopropanating Reagents: Synthesis, Reactivity, and Stability Studies of Iodomethylzinc Phenoxides
Author(s) -
Charette André B.,
Francoeur Sébastien,
Martel Jonathan,
Wilb Nicole
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001215)39:24<4539::aid-anie4539>3.0.co;2-9
Subject(s) - reactivity (psychology) , reagent , chemistry , organic chemistry , medicine , alternative medicine , pathology
A valuable alternative to the traditional Simmons–Smith reagents is offered by the title compounds, as a result of their ease of preparation and high reactivities towards unfunctionalized olefins (see scheme).