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Hybrid Coordination Polymers—Metal Oxide Compounds with Chiral Structures
Author(s) -
Zheng LiMin,
Whitfield Tabatha,
Wang Xiqu,
Jacobson Allan J.
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001215)39:24<4528::aid-anie4528>3.0.co;2-h
Subject(s) - point of zero charge , oxide , metal , coordination polymer , chemistry , ligand (biochemistry) , crystallography , vanadium oxide , polymer , coordination complex , vanadium , metal ions in aqueous solution , ion , inorganic chemistry , coordination number , stereochemistry , crystal structure , organic chemistry , biochemistry , receptor
Helical tubes , made up from four chains each of composition M(pzc) + (M=Co, Ni), are present in compounds of Co or Ni ions coordinated by the ligand 2‐pyrazinecarboxylic acid (2‐pzc) and vanadium oxide chains. Compounds 1 and 2 have chiral structures and compound 3 contains equal numbers of left‐ and right‐handed helices.