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Highly Selective Ring‐Opening/Cross‐Metathesis Reactions of Norbornene Derivatives Using Selenocarbene Complexes as Catalysts
Author(s) -
Katayama Hiroyuki,
Urushima Hideto,
Nishioka Tsuneo,
Wada Chikaya,
Nagao Masato,
Ozawa Fumiyuki
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001215)39:24<4513::aid-anie4513>3.0.co;2-c
Subject(s) - norbornene , metathesis , catalysis , chemistry , ring (chemistry) , ring opening metathesis polymerisation , combinatorial chemistry , salt metathesis reaction , polymer chemistry , organic chemistry , polymerization , polymer
Fischer‐type ruthenium carbene complexes bearing a selanylcarbene ligand efficiently catalyze ring‐opening/cross‐metathesis (ROCM) of norbornene derivatives with phenyl vinyl selenide to give the ROCM products in high selectivities (see scheme).