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A Tandem Sulfur Transfer/Reduction/Michael Addition Mediated by Benzyltriethylammonium Tetrathiomolybdate
Author(s) -
Prabhu Kandikere Ramaiah,
Sivanand Pennadam S.,
Chandrasekaran Srinivasan
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001201)39:23<4316::aid-anie4316>3.0.co;2-e
Subject(s) - domino , tandem , sulfur , sequence (biology) , redox , reduction (mathematics) , chemistry , michael reaction , combinatorial chemistry , organic chemistry , biochemistry , materials science , catalysis , geometry , mathematics , composite material
In a domino‐type reaction sequence , the redox chemistry of [BnNEt 3 ] 2 MoS 4 is exploited in forming and cleaving disulfides (see scheme). This strategy has been utilized effectively in a one‐pot tandem sulfur transfer/reduction/Michael addition sequence.