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A Novel CSiP Ring from the Reaction of a Complexed Phosphinidene and a Silene
Author(s) -
Vlaar Mark J. M.,
Ehlers Andreas W.,
de Kanter Frans J. J.,
Schakel Marius,
Spek Anthony L.,
Lutz Martin,
Sigal Nadejda,
Apeloig Yitzhak,
Lammertsma Koop
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001117)39:22<4127::aid-anie4127>3.0.co;2-b
Subject(s) - phosphinidene , ring (chemistry) , chemistry , silene , stereochemistry , photochemistry , organic chemistry , biology , genetics
A phosphasilirane was synthesized from the addition of a terminal phosphinidene complex with a silene [Eq. (1)]. Both starting materials are reactive intermediates that are simultaneously generated in situ. The first X‐ray structure analysis of a complexed phosphasilirane and the calculated strain energy for the parent system give insight into the stability of this new CPSi ring system.