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Diels–Alder Type Addition of 1,3‐Dienes to a Disulfide Bridging Ligand in Diruthenium Complexes
Author(s) -
Sugiyama Hiroyasu,
Lin YongShou,
Matsumoto Kazuko
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001117)39:22<4058::aid-anie4058>3.0.co;2-5
Subject(s) - ruthenium , chemistry , disulfide bond , conjugated system , bridging (networking) , cycloaddition , ligand (biochemistry) , bridging ligand , diene , diels–alder reaction , ring (chemistry) , stereochemistry , organic chemistry , molecule , catalysis , polymer , computer science , natural rubber , computer network , biochemistry , receptor
The dienophilic disulfide ligands that bridge the two Ru centers in the ruthenium dinuclear complexes react with conjugated dienes through a Diels–Alder cycloaddition to give new species which carry the C 4 S 2 six‐membered ring (see scheme).