Premium
A Triangular Triplatinum Complex with Electron‐Releasing SiPh 2 and PMe 3 Ligands: [{Pt( μ ‐SiPh 2 )(PMe 3 )} 3 ]
Author(s) -
Osakada Kohtaro,
Tanabe Makoto,
Tanase Tomoaki
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001117)39:22<4053::aid-anie4053>3.0.co;2-z
Subject(s) - platinum , thermal decomposition , chemistry , cluster (spacecraft) , silylation , silylene , metal , crystallography , decomposition , silicon , organic chemistry , catalysis , computer science , programming language
A platinum–silylene complex is implicated in the generation of the triangular platinum cluster 1 by thermolysis of a bis(silyl)‐Pt II complex. Although 1 contains only electron‐releasing ligands, X‐ray structural data, NMR studies, and MO calculations on a model complex are consistent with the presence of Pt 0 centers and metal–metal bonds.