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Structural, Electrochemical, and Photophysical Properties of Gallium( III ) 5,10,15‐Tris(pentafluorophenyl)corrole
Author(s) -
Bendix Jesper,
Dmochowski Ivan J.,
Gray Harry B.,
Mahammed Atif,
Simkhovich Liliya,
Gross Zeev
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001117)39:22<4048::aid-anie4048>3.0.co;2-7
Subject(s) - corrole , tris , gallium , electrochemistry , chemistry , photochemistry , organic chemistry , electrode , biochemistry
High quantum yields are found for the prototype metallocorrole 1 , which is readily prepared from GaCl 3 and tris(pentafluorophenyl)corrole. The crystallographic and electronic structures of 1 are reported as well as the simple generation of its π‐cation radical complex by chemical oxidation and the characteristic spectroscopic features of this ion.