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(CN 3 H 6 ) 4 [Zn 3 (SeO 3 ) 5 ]: The First Organically Templated Selenite
Author(s) -
Harrison William T. A.,
Phillips Mark L. F.,
Stanchfield Jesse,
Nenoff Tina M.
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001103)39:21<3808::aid-anie3808>3.0.co;2-e
Subject(s) - selenium , hydrogen bond , chemistry , ring (chemistry) , crystallography , molecule , organic chemistry
A completely different structure to that of any “inorganic” selenite is exhibited by the organically templated title compound. One of the guanidinium cations displays a particularly clear template effect in occupying a 12‐ring window and bonding to the inorganic network by way of N−H⋅⋅⋅O hydrogen bonds (see picture).