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The First Dendrimer‐Based Enantioselective Fluorescent Sensor for the Recognition of Chiral Amino Alcohols
Author(s) -
Pugh Vincent J.,
Hu QiaoSheng,
Pu Lin
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001016)39:20<3638::aid-anie3638>3.0.co;2-g
Subject(s) - dendrimer , fluorescence , enantioselective synthesis , chemistry , combinatorial chemistry , organic chemistry , catalysis , optics , physics
Enhanced fluorescence as well as more sensitive fluorescence responses towards chiral quenchers are observed for dendrimer 1 (R= t Bu) than its chiral core binaphthol unit. The fluorescence of the chiral dendrimer 1 is quenched efficiently and enantioselectively by chiral amino alcohols such as 2 .