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Novel Mode of C−C Bond Cleavage of Norbornadiene on a Dinuclear Ruthenium Complex
Author(s) -
Ohki Yasuhiro,
Suzuki Hiroharu
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001002)39:19<3463::aid-anie3463>3.0.co;2-g
Subject(s) - norbornadiene , ruthenium , chemistry , cleavage (geology) , bicyclic molecule , bond cleavage , stereochemistry , photochemistry , materials science , organic chemistry , catalysis , fracture (geology) , composite material
Unprecedented activation of two C−C bonds of norbornadiene on a dinuclear ruthenium complex is reported in which the bicyclic structure of norbornadiene is transformed into a linear C 7 chain (structure of the resulting complex is shown).