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A New Type of Supramolecular Compound: Molybdenum‐Oxide‐Based Composites Consisting of Magnetic Nanocapsules with Encapsulated Keggin‐Ion Electron Reservoirs Cross‐Linked to a Two‐Dimensional Network
Author(s) -
Müller Achim,
Das Samar K.,
Kögerler Paul,
Bögge Hartmut,
Schmidtmann Marc,
Trautwein Alfred X.,
Schünemann Volker,
Krickemeyer Erich,
Preetz Wilhelm
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20001002)39:19<3413::aid-anie3413>3.0.co;2-q
Subject(s) - supramolecular chemistry , nanocapsules , molybdenum , oxide , ion , metal , molybdenum oxide , materials science , cluster (spacecraft) , metal organic framework , icosahedral symmetry , chemistry , nanotechnology , chemical engineering , crystallography , inorganic chemistry , crystal structure , nanoparticle , organic chemistry , metallurgy , engineering , adsorption , computer science , programming language
Nanosized metal‐oxide‐based composites —novel supramolecular entities—have been assembled and even cross‐linked under one‐pot conditions. The supramolecular entity (see picture) consists of a paramagnetic icosahedral capsule of the type {Mo VI 72 Fe III 30 } as a host which encloses a potential electron‐reservoir noncovalently bonded guest, the reduced Keggin cluster [H 2 PMo 12 O 40 ] 3− .