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Synthesis, Structure, and Reactivity of a 1σ 4 ,3σ 2 ‐Diphosphaallene
Author(s) -
Kato Tsuyoshi,
Gornitzka Heinz,
Baceiredo Antoine,
Bertrand Guy
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000915)39:18<3319::aid-anie3319>3.0.co;2-m
Subject(s) - ylide , reactivity (psychology) , chemistry , reagent , molecule , double bond , combinatorial chemistry , stereochemistry , polymer chemistry , organic chemistry , medicine , alternative medicine , pathology
The first heterocumulene featuring both an ylide bond and a π double bond has been isolated. This highly functionalized molecule appears to be a very versatile and selective reagent (see scheme).