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Redox‐Switched Control of Binding Strength in Hydrogen‐Bonded Metallocene Complexes
Author(s) -
Carr Jonathan D.,
Coles Simon J.,
Hursthouse Michael B.,
Light Mark E.,
Tucker James H. R.,
Westwood Joanna
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000915)39:18<3296::aid-anie3296>3.0.co;2-u
Subject(s) - metallocene , hydrogen bond , glutaric acid , redox , hydrogen , polymer chemistry , materials science , chemistry , molecule , inorganic chemistry , organic chemistry , polymerization , polymer
Switching the charge of metallocene receptors (M=Fe, Co) on or off controls their binding strength with glutaric acid (GA; see scheme). These receptors containing amidopyridine units bind glutaric acid through hydrogen‐bonding interactions.