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A Graphite‐Like Complex with Large Cavities Constructed with the Complex Ligand [Ni II (bpca) 2 ]
Author(s) -
Kamiyama Asako,
Noguchi Tomoko,
Kajiwara Takashi,
Ito Tasuku
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000901)39:17<3130::aid-anie3130>3.0.co;2-i
Subject(s) - ligand (biochemistry) , graphite , amine gas treating , stoichiometry , crystallography , chemistry , ion , stereochemistry , materials science , organic chemistry , biochemistry , receptor
Interpenetration is avoided in the graphite‐like structure constructed by the complex ligand [Ni II (bpca) 2 ] (bpca=bis(2‐pyridylcarbonyl)amine) and iron( II ) ions (see picture). The structure contains large cavities at the centers of the rings. Controlling the reaction stoichiometry and the choice of solvents enables this complex to be prepared selectively in preference to related discrete trinuclear and one‐dimensional complexes.