Premium
Synthesis and Characterization of Iron Silasesquioxane Phosphane Complexes
Author(s) -
Liu Fuchen,
John Kevin D.,
Scott Brian L.,
Baker R. Tom,
Ott Kevin C.,
Tumas William
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000901)39:17<3127::aid-anie3127>3.0.co;2-f
Subject(s) - characterization (materials science) , chemistry , materials science , nanotechnology
Iron centers in highly siliceous environments have been isolated by the reaction of incompletely condensed polyhedral silasesquioxanes with iron phosphane complexes in benzene. Among the new compounds is the oxo‐bridged dianionic dimer 1 . Single‐crystal X‐ray structures and preliminary reactivity studies are described.