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Uranium Hexakisamido Complexes
Author(s) -
Meyer Karsten,
Mindiola Daniel J.,
Baker Thomas A.,
Davis William M.,
Cummins Christopher C.
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000901)39:17<3063::aid-anie3063>3.0.co;2-0
Subject(s) - uranium , environmental science , geology , radiochemistry , chemistry , materials science , metallurgy
Minimal structural changes accompany the oxidation of the paramagnetic uranium( V ) anion [U(dbabh) 6 ] − to the neutral, diamagnetic counterpart [U(dbabh) 6 ] (see structure). These two T h ‐symmetric complexes, which were synthesized starting from 2,3:5,6‐dibenzo‐7‐azabicyclo[2.2.1]hepta‐2,5‐diene (Hdbabh), are the first isolable homoleptic hexakisamido complexes of uranium( V ) and ( VI ).